Why a sealed surface changes the question
A patio, path or wall that has already been painted or sealed is not a blank surface. Whatever was put down before is still there, sitting between the masonry and anything you apply next, and it decides how well a new coating bonds, how it breathes and how long it lasts.
The difficulty is that nobody arrives knowing what that earlier coating actually is. It may have gone on years ago, by a previous owner or a contractor who left no record of what they used, and one clear coating looks much like another once it has weathered.
Why no datasheet covers this situation
A manufacturer's figures describe how its product performs on bare concrete, bare render or bare stone, because that is the substrate it controls and can test. It has no way of testing every coating a stranger might have applied years earlier, so a datasheet rarely says anything about painting over an unidentified prior layer. The standards behind slip resistance and vapour behaviour work the same way: they describe a product on a known substrate.
That gap is why the question cannot be settled from a tin or a standard on its own. What is already on the surface has to be identified first, because that is what determines whether a new coat will stick, let moisture through, or lift within a season.
Working out what's already on the surface
What's already on the surface decides whether a new coat will bond or come straight back off, and you can find out most of it without buying anything. The three checks below work best in this order, because each one only means something once you've ruled out what came before.
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See what the water does
Pour a small cup of water onto the surface and watch it for a minute or two. This first check only tells you whether anything is sitting on top of the masonry at all, before you go near a solvent or look at the finish.
A sealer that's beading water lightly rather than strongly can still be a coating, just an older one. A faint bead doesn't rule one out.
It beads and sits on topWater forming raised beads means something is stopping it soaking in. That points to a sealer or a paint film.
It soaks straight inWater disappearing into the surface within a minute or so suggests the masonry is taking it in directly, which can mean an untreated surface or a sealer that has already worn through.
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Rub a solvent on a hidden patch
On a corner or edge that won't be seen, rub a cloth dampened with methylated spirit or white spirit over a small area and check both the cloth and the surface afterwards.
Test on a spot that won't be seen. Solvent can dull or discolour some finishes permanently.
The finish softens or comes off on the clothA film lifting, or colour transferring onto the cloth, points to a solvent-based or acrylic coating sitting on the surface.
Nothing changesNo softening and no colour transfer can mean bare masonry, an impregnating sealer that has soaked in rather than sitting on top, or a tougher coating such as an epoxy or polyurethane that solvent won't touch.
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Look at the sheen and the wear pattern
Stand back and look at how light sits across the surface, and how evenly any wear or flaking has spread.
If you can lift a flake and turn it over, a second colour underneath tells you there's more than one coat on the surface.
A uniform sheen with no flakingAn even, slightly glossy or satin look across the whole area usually means a coating that is still largely intact.
Patchy sheen, flaking edges, or a chalky residue on your handUneven patches, lifting edges or a powder that transfers to your hand when you touch it point to a coating that is breaking down.
These checks narrow down what you're dealing with. None of them names the product, the brand or how old it is, and some possibilities only separate out once you expose a small section and look at what's underneath.
When removal is the better option
When a patch test is the most you can do
If the water test, the solvent test and a close look at the surface don't settle the question, try a small test coat in a corner that won't show. Leave it for several days before checking adhesion and any change in sheen or colour. A patch that lifts, blisters or stays tacky is telling you the existing coating and the new one don't sit well together, and that result holds across the rest of the surface too.
Signs that point towards removal
Some surfaces answer the question for you. Flaking, peeling or powdering paint means the bond to the substrate has already failed, and a fresh coat on top sits on that problem. A coating that turns sticky, soft or patchy under the solvent test usually means a different chemical family is underneath, one a new coat may not bond to cleanly. On a lime render the stakes are higher: trapping moisture behind the wrong coating can damage the render itself, a point covered on the page about concrete, natural stone and lime render.
What removal involves
Removing an existing coating means getting back to bare substrate before anything new goes on, usually with mechanical stripping or a chemical stripper matched to what's already there. It takes longer than overcoating, but it's the only route once a patch test has failed or the surface is already breaking up. Once the substrate is bare, deciding what to put on it is the question answered on the page comparing paint and sealant.
Weighing the two routes
Overcoating only makes sense where the existing layer is sound and sits well with what you're adding. Where it isn't, stripping it back costs more time now but avoids redoing the job within a season or two. A patch test that fails, or a surface that's flaking, blistering or going soft and tacky under solvent, is telling you which route to take.